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During the 1970 s, however, when consols sank in price to below 25, the old dreams of capital gains seemed to fade, the low coupon became unpopular, and at times consols sold to yield more than did high-coupon issues The yield on consols after 1918, therefore, can no longer be taken as typical of the market, although the difference usually was not large In Table 59, prices and yields of consols are given for the sake of continuity These consol yields are supplemented by a band of yields bounded by two series that give the simultaneous lowest and highest interest yields of all British government securities with maturities of thirty years or more on each December 31 This band should satisfactorily picture the trend and level of long-term English government bond yields.

relative amounts of allophanate and biuret crosslinks in the polymer depend on the relative amounts of urea and urethane groups (which, in turn, depends on the relative amounts of diamine and diol) and reaction conditions. There is a greater tendency to biuret linkages since the urea N is more reactive than the urethane N H H. Trimerization of isocyanate groups to form isocyanurates also occurs and serves as an additional source of branching and crosslinking:

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Taking it a little further, and though not a chance art, the chopping and hot-rodding, repainting, rewiring, and renaming of that 57 Chevy you see at the car show is done in the same vein as circuit-bending. Each effort reflects a desire to push the limits of a thing. I recently spoke at a circuit-bending convention in New York City where, as at the car shows, industry dollars propped up the event! Bending has come a long way from the night in the 1960s when the band and I had to fistfight our way out of that performance-gone-bad with the Elvis fans at our heels. I recall that we decided not to play there again.

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One complication involves the speculative yields provided during the high bond markets of the 1930 s and 1940 s by premium issues, which might or might not be called at the earliest redemption date The band of yields is based on the assumption that premium issues will be redeemed as soon as possible The table provides, as an alternative calculation, maximum current yields of bonds selling at premiums These were yields that might be realized if interest rates rose and these issues were not called Just this happened These higher current yields in the 1930 s and 1940 s were so much above the market that they cannot be considered as the.

These reactions present a complexity in carrying out polymerization. Simultaneously, we have the ability to vary polymer properties over a wide range by control of the relative amounts of reactants and the polymerization conditions. Further control of the nal product is achieved by choice of monomers. Most polyurethanes involve a macroglycol (a low-molecular-weight polymer with hydroxyl end groups), diol or diamine, and diisocyanate. The macroglycol (also referred to as a polyol) is a polyether or polyester synthesized under conditions that result in two or more hydroxyl end groups. (Details of polyurethane synthesis involving macroglycols are described in Sec. 2-13c.) The diol monomers include ethylene glycol, 1,4-butanediol, 1,6-hexanediol, and p-di(2-hydroxyethoxy)benzene. The diamine monomers include diethyltoluenediamine, methylenebis(p-aminobenzene), and 3,30 dichloro-4,40 -diaminodiphenylmethane. The diisocyanate monomers include hexamethylene diisocyanate, toluene 2,4- and 2,6-diisocyanates, and naphthalene 1,5-diisocyanate. Alcohol and isocyanate reactants with functionlity greater than 2 are also employed. The extent of crosslinking in polyurethanes depends on a combination of the amount of polyfunctional monomers present and the extent of biuret, allophanate, and trimerization reactions [Dusek, 1987]. The latter reactions are controlled by the overall stoichiometry and the speci c catalyst present. Stannous and other metal carboxylates as well as tertiary amines are catalysts for the various reactions. Proper choice of the speci c catalyst result in differences in the relative amounts of each reaction. Temperature also affects the extents

of the different reactions. Polymerization temperatures are moderate, often near ambient and usually no higher than 100 120 C. Signi cantly higher temperatures are avoided because polyurethanes undergo several different types of degradation reactions, such as

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