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That the golden age of invention is dead is a romantic notion at best True, corporate research and development labs seem to outdo the practical capabilities of garage tinkerers But the truth is that we live in a rich world of discovery, right here, every day Just depends on where you look There is a principle discussed among all inventors, unnamed heretofore A principle of simultaneous discovery I discussed it most recently with blacksmith Howard McDaniels of Lebanon, Ohio, a modern smith whose work spans traditional utilitarian repair and fabrication to artistic ironwork to high-precision pieces for the nuclear industry Howard s example of this principle was how similar developments in metallurgy occurred, unrelated, in various places around the planet at the same time I call this technological/sociological time-wave the threshold of invention.

prevailing rates on long-term bonds that investors expected to receive They are listed in the table, but are not included in the corresponding graph in Chart 53 COMPARISON WITH UNITED STATES BOND YIELDS Chart 53 pictures this band of December 31 yields on long British government bonds and compares them with the annual average of yields of American prime corporate bonds Comparison with US government bond yields would be preferable, but the circulation privilege before 1917, partial tax exemption from 1917 to 1941, and the frequent lack of new long-term US government bond issues deprive us of a usable series for several decades The series on prime American corporate bond yields is reasonably uniform, and the bonds included in the series were of very high quality.

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as well as decomposition back to the alcohol and isocyanate monomers. Overall control in the synthesis of polyurethane foamed products also requires a balance between the polymerization crosslinking and blowing processes. An imbalance between the chemical and physical processes can result in a collapse of the foamed structures (before solidi cation by crosslinking and/or cooling) or imperfections in the foam structures, which yields poor mechanical strength and performance. The wide variations possible in synthesis give rise to a wide range of polyurethane products including exible and rigid foams and solid elastomers, extrusions, coatings, and adhesives. Polyurethanes possess good abrasion, tear, and impact resistance coupled with oil and grease resistance. The global production of polyurethanes was more than 15 billion pounds in 1997. Flexible foamed products include upholstered furniture and auto parts (cushions, backs, and arms), mattresses, and carpet underlay. Rigid foamed products with a closedcell morphology possess excellent insulating properties and nd extensive use in commercial roo ng, residential sheathing, and insulation for water heaters, tanks, pipes, refrigerators, and freezers. Solid elastomeric products include forklift tires, skateboard wheels, automobile parts (bumpers, fascia, fenders, door panels, gaskets for trunk, windows, windshield, steering wheel, instrument panel), and sporting goods (golf balls, ski boots, football cleats). Many of these foam and solid products are made by reaction injection molding (RIM), a process in which a mixture of the monomers is injected into a mold cavity where polymerization and crosslinking take place to form the product. Reaction injection molding of polyurethanes, involving low-viscosity reaction mixtures and moderate reaction temperatures, is well suited for the economical molding of large objects such as automobile fenders. (Many of the elastomeric polyurethane products are thermoplastic elastomers; see Sec. 2-13c.)

2-12f Polysiloxanes Polysiloxanes, also referred to as silicones, possess an unusual combination of properties that are retained over a wide temperature range ( 100 to 250 C). They have very good lowtemperature exibility because of the low Tg value ( 127 C). Silicones are very stable to high temperature, oxidation, and chemical and biological environments, and possess very good low-temperature exibility because of the low Tg values ( 127 C for dimethylsilox ane), a consequence of the long Si bond (1.64 A compared to 1.54 A for C and O C) the wide Si Si bond angle (143 compared to 109.5 for C C). The Si bond is O C O stronger than the C bond ($450 vs. 350 kJ/mol) and siloxanes are very stable to high C temperature, oxidation, chemical and biological environments, and weathering, and also possess good dielectric strength, and water repellency. The United States production of polysiloxane uids, resins, and elastomers was about 800 million pounds in 2001. Fluid applications include uids for hydraulics, antifoaming, water-repellent nishes for textiles,

surfactants, greases, lubricants, and heating baths. Resins are used as varnishes, paints, molding compounds, electrical insulation, adhesives, laminates, and release coatings. Elastomer applications include sealants, caulks, adhesives, gaskets, tubing, hoses, belts, electrical insulation such as automobile ignition cable, encapsulating and molding applications, fabric coatings, encapsulants, and a variety of medical applications (anti atulents, heart valves, encasing of pacemakers, prosthetic parts, contact lenses, coating of plasma bottles to avoid blood coagulation). Silicone elastomers differ markedly from other organic elastomers in the much greater effect of reinforcing llers in increasing strength properties. Polysiloxane uids and resins are obtained by hydrolysis of chlorosilanes such as dichlorodimethyl-, dichloromethylphenyl-, and dichlorodiphenylsilanes [Brydson, 1999; Hardman and Torkelson, 1989]. The chlorosilane is hydrolyzed with water to a mixture of chlorohydroxy and dihydroxysilanes (referred to as silanols), which react with each other by dehydration and dehydrochlorination. The product is an equilibrated mixture of approximately equal

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